Studying the characteristics of solar X-ray emission for proton flare will provide an important way and method for proton event warning. The observational data of proton flares and relevant X-ray emission obtained by GOES and SMMsatellites during the 21st Solar Maximum are analysed in this paper. It shows that, for most proton flares, the hard X-ray emission has following properties: the peak flux F
HX≥10
4c/s, duration time Tn≥103sec, maximum X-ray photon energy Ex≥300 keV, average spectral index<3.5, high energy time delay TL> 10 sec, integral flux F0>106counts, rising time TR>102sec. By using these characteristic parameters to warn the proton events, the a correct prediction rate of 94% and a false prediction rate of 40% are obtained respectively.